Here are the PS5 Controller Settings for NHL 23 with screenshots to make it easier to see how to do certain tasks. EA Sports also publishes this for NHL 22, https://www.ea.com/able/resources/nhl/nhl-22/ps5/controls, but hasn’t for NHL 23 yet.
Controller Settings Overview
Offense Overview
Offense 1
Offense 2
Defense Overview
Defense
Goalie Overview
Goalie
Fighting
Net Battles